Method for preparing tris(ether-amine)  

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Publication number: US6403834 (B1)
Publication date: 2002-06-11
Inventor(s): ALAS MICHEL [FR]; BOUNIOT ALBERT [FR]
Applicant(s): RHONE POULENC CHIMIE [FR]
Classification:  
- international: C07B61/00; C07C213/02; C07C217/08; C07C217/28; C07B61/00; C07C213/00; C07C217/00; C07C217/00; (IPC1-7): C07C209/16; C07C213/02
- European: C07C213/02
Application number: US20010831401 20010723 
Priority number(s): FR19980014081 19981109; WO1999FR02745 19991109
   
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Also published as:
  FR2785607  (A1)  
  JP2002529440  (T)  
  WO0027796  (A1)  
  ES2214065  (T3)  
  EP1129065  (A1)  
 
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Cited documents:
  US4408075 (A)  
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Abstract of US 6403834  (B1)
The invention concerns a method for preparing tris(ether-amines) of formula (I): N[A-O-(B-O)n-R]3 wherein R, A, B and n are as defined in Claim 1, comprising the reaction, in liquid phase, of an alkylene-glycol monoether of formula (II): HO-A-O-(B-O)nR wherein R, A, B and n are as defined in Claim 1, with an ammonolysis agent selected among ammonia and an etheramine of formula (I'): H3-pN[A-O-(B-O)nR]p wherein: A, B, n and R are as defined in Claim 1 and p represent 1 or 2, at a temperature ranging between 100 and 250 DEG C., by contacting reagents with a hydrogenation-dehydrogenation catalyst.

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